Principle: A chemical reaction based on oxidation causing a coloured structure to transform into a less coloured structure or even a colourless material.
Hydrogen peroxide breaks down and releases free radicals. These free radicals split double bonds causing cyclic compounds to open. This changes the molecular structure and causes a shift of spectrum of absorption.
Discoloration
External causes: drinks: tea, coffee, wine, bevarages, Tobacco: these can be helped with prophylactic measures e.g. brushing
Internal causes: drugs(tetracylines, fluorides), trauma, endodontic treatment: these can be helped with bleaching
Examples of dental bleach
- Hydrogen Peroxide (3%-35%)
- Carbamide Peroxide (10%-30%) >>> urea + hydrogen peroxide
- Sodium Perborate >>> sodium metaborate + hydrogen peroxide
- Calcium Peroxide
Methods of bleaching
- External bleaching for artificial discoloration
- Direct (In-office)
- Assisted (Home)
- Internal Bleaching/Non-Vital
- Intracoronal
External Bleaching
Direct (In-office)
- This procedure is provided by a suitably trained dental professional in a clinical setting
- Uses a high concentration of peroxide solution e.g 35% hydrogen peroxide applied directly to the teeth
- Sometimes a heat or light source is used
- Requires very good isolation to prevent chemical damage to the soft tissues
- Useful for patients who struggle with home bleaching
- Disadvantages: difficult to control extent of whitening- risk of under/over bleaching, risk of severe post-op sensitivity
Assisted (Home)
- Involves taking an alginate impression of the teeth and having a lab fabricate a bleaching tray
- Requires patient to take and apply the peroxide bleach to the trays and wear at home; usually overnight
- Low concentrations used e.g.6% Hydrogen peroxide 10-20% Carbamide Peroxide
- Disadvantage: takes longer – weeks-months to achieve desired results
Internal (Non-vital) Bleaching
Intracoronal (In-office)
- Used in endodontically treated teeth
- Involves sealing bleach within the pulp chamber of the tooth and restored temporarily
- The procedure is repeated every 3-4 days
- Generally, uses hydrogen peroxide or sodium perborate
- Disadvantage – requires a well-sealed root canal to prevent bleach reaching the periapical space (seal with GI/composite)